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- W2095355303 abstract "The layered oxide thermoelectric material β-Na0.67CoO2 has been studied by powder neutron diffraction, electric and magnetic measurements. This compound includes an edge-sharing CoO6 slab and a highly vacant Na+ sheet in a unit cell (space group symmetry C2/m, a=4.9023(4) Å, b=2.8280(2) Å, c=5.7198(6) Å and β=105.964(6)° at 300 K). The evaluated formal valence of cobalt ion, +3.33(1), is ascribed to the coexistence of Co3+ and Co4+ in the ratio 2:1. Polycrystalline β-Na0.67CoO2, a p-type thermoelectric material, exhibits metallic behavior of the electric resistivity below 300 K. The Curie–Weiss-type magnetic susceptibility indicates antiferromagnetic interactions between magnetic cobalt ions in the edge-sharing CoO6 slab." @default.
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- W2095355303 date "2002-06-01" @default.
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- W2095355303 title "Crystal Structure, Electric and Magnetic Properties of Layered Cobaltite β-NaxCoO2" @default.
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- W2095355303 doi "https://doi.org/10.1006/jssc.2002.9578" @default.
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