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- W2095357731 abstract "We studied the adsorption behavior of radioactive cesium (Cs) by the non-mica minerals kaolinite, halloysite, chlorite, montmorillonite, mordenite, MnO2, TiO2, Al2O3, and FeOOH to elucidate the environmental behavior of radioactive Cs fallout from the Fukushima Daiichi Nuclear Power Plant in the Tohoku region of Japan. The adsorption and desorption experiments of Cs on the minerals were carried out at the Cs concentrations 1 × 10−4, 1 × 10−5, and 2 × 10−9 mole L−1 at pH 5.5. The desorption of Cs from the minerals was examined using 0.1 mole L−1 LiCl, NaCl, KCl, RbCl, and CsCl solutions. The sequential desorption was examined using a 0.1 mole L−1 LiCl solution, a 1 mole L−1 KCl solution, and a 1 mole L−1 HCl solution. The distribution coefficient (K d) for the minerals at the Cs concentration 10−9 mole L−1 was in the order of mordenite > illite > montmorillonite, sericite, MnO2, kaolinite, and halloysite > chlorite, TiO2, Al2O3, and FeOOH, differing from the order observed at higher Cs concentrations. After the sequential desorption by the three reagent solutions, the residual fraction of Cs was higher at the Cs concentration 10−9 mole L−1 than at higher concentrations. Approximately 40%, 40%, 50%, and 25% of the adsorbed Cs were residual in montmorillonite, mordenite, MnO2, and kaolinite, respectively, after the sequential desorption. These results strongly suggest that (1) radioactive Cs at 10−9 mole L−1 is more strongly associated with the non-mica minerals than at higher concentrations of 1 × 10−4 and 1 × 10−5 mole L−1, and (2) the non-mica minerals montmorillonite, mordenite, kaolinite, and MnO2 contributed to the fixation of the radioactive Cs fallout on Fukushima soil." @default.
- W2095357731 created "2016-06-24" @default.
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- W2095357731 date "2013-04-01" @default.
- W2095357731 modified "2023-10-16" @default.
- W2095357731 title "Adsorption behavior of radioactive cesium by non-mica minerals" @default.
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- W2095357731 doi "https://doi.org/10.1080/00223131.2013.773164" @default.
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