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- W2095378045 abstract "Novel, Sr-substituted A-site ordered perovskites with GdBa0.5Sr0.5Co2−xFexO5+δ (0 ≤ x ≤ 2) chemical composition were studied, and results of measurements of their phase composition, crystal structure, oxygen content δ, transport properties and chemical stability in relation to ceria electrolyte are presented in this work. It was found that despite 50% substitution of Ba by Sr, the tendency of ordering in A-sublattice is retained in Co-rich materials, but with the increase of iron content, a significant amount of unordered, but also perovskite phase appears. Compounds with high Co content possess highest electrical conductivity, which for GdBa0.5Sr0.5Co2O5+δ greatly exceeds 1000 S cm−1 at temperatures above 400 °C. Seebeck coefficient remains positive for all studied compositions in 25–850 °C temperature range, indicating dominance of holes as main charge carriers. The double perovskite structure is responsible for a high deviation from the oxygen stoichiometry in studied materials, which increases considerably above 300 °C. GdBa0.5Sr0.5Co1.5Fe0.5O5+δ cathode material was selected for additional studies, which included evaluation of thermal expansion, determination of chemical diffusion coefficient D and surface exchange reaction coefficient K and electrochemical measurements in a custom made, electrolyte-supported Intermediate Temperature Solid Oxide Fuel Cells (IT-SOFCs). At 800 °C value of D is close to 10−5 cm2 s−1, which together with high concentration of oxygen vacancies points to a high ionic conductivity of the material. Together with total electrical conductivity exceeding 400 S cm−1 in 600–800 °C range, and with high chemical stability in relation to ceria electrolyte, the observed properties are attractive from the point of view of application. However, due to a large chemical expansion, in order to obtain good adhesion between cathode and electrolyte layers, composite cathodes, consisting of GdBa0.5Sr0.5Co1.5Fe0.5O5+δ and ceria electrolyte powders had to be used. Recorded power density of IT-SOFC cell was about 0.27 W cm−2 at 800 °C, while the performed impedance spectroscopy studies revealed that ohmic component was the dominant one above 700 °C in total polarization of the cell." @default.
- W2095378045 created "2016-06-24" @default.
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- W2095378045 date "2013-01-01" @default.
- W2095378045 modified "2023-10-01" @default.
- W2095378045 title "Characterization of novel GdBa0.5Sr0.5Co2−xFexO5+δ perovskites for application in IT-SOFC cells" @default.
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- W2095378045 cites W1970586383 @default.
- W2095378045 cites W1974072175 @default.
- W2095378045 cites W1976568090 @default.
- W2095378045 cites W1982052296 @default.
- W2095378045 cites W1983909332 @default.
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- W2095378045 cites W2003867443 @default.
- W2095378045 cites W2004784592 @default.
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- W2095378045 cites W2018490218 @default.
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- W2095378045 doi "https://doi.org/10.1016/j.ijhydene.2012.10.085" @default.
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