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- W2095408503 abstract "Abstract Darstellung und Kristallstruktur von SnTl 4 Se 3 werden beschrieben. Die Verbindung kristallisiert in der Raumgruppe P4/ncc als niedersymmetrische Verzerrungsvariante des In 5 Bi 3 ‐Typs, der selbst eine isopuntale Unterfamilie des Cr 5 B 3 ‐Typs ist: a = 852,2(2) pm, c = 1 272,2(6) pm, c/a = 1,49, Z = 4. Es treten kurze SnSe‐Abstände in längs [001] verlaufenden [SnSe 2/2 ]‐Ketten (311 pm, 326 pm) und kurze TlSe‐Abstände in quasimolekularen, gewinkelten Baugruppen Tl 2 Se auf (300 pm, 313 pm, 347 pm). Die Verbindung ist halbleitend; die Leitfähigkeiten einiger verwandter Verbindungen werden ebenfalls vorgestellt. Um Vergleichswerte für Tl 1+ ‐Ionen mit quadratisch‐antiprismatischer Se‐Koordination zu erhalten, ist die Struktur der bekannten Verbindung TlSe erstmals mittels Einkristallen verfeinert worden." @default.
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- W2095408503 title "Darstellung und Kristallstruktur von SnTl4Se3 mit einer Anmerkung zu TlSe" @default.
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