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- W2095427296 abstract "T has recently been demonstrated in the aerospace literature considerable interest concerning the surface recombination of atoms. The analyses of this phenomenon have been carried out within the framework of boundarylayer theory and have involved a boundary condition at the exposed surface relating the normal gradient of atom mass fraction and the atom mass fraction itself. It is generally stated and/or recognized that these analyses for a binary system apply as well to more complicated systems, provided that the concentration of reactants and products is vanishingly small.' 7 It is the purpose of the present note to develop the boundary conditions when this latter assumption is not employed 4 We want to state at the outset that some of the results presented here are perhaps known to chemical engineers as indicated, for example, by Ref. 9. However, the implications of the condition of steady state and, further, of the condition of local adsorption equilibrium leading to the surface boundary conditions for diffusive flows, appear to be new. In any case, it may be useful to the aerospace community to have readily available the present results. § For generality, we consider a set of surf ace -catalyzed reactions of the form" @default.
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- W2095427296 date "1965-06-01" @default.
- W2095427296 modified "2023-10-16" @default.
- W2095427296 title "Boundary conditions for some surface-catalyzed reactions" @default.
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- W2095427296 doi "https://doi.org/10.2514/3.3075" @default.
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