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• W2095437056 abstract "Triphenylphosphine reacts with dialkyl acetylenedicarboxylates in the presence of heterocyclic compounds, such as 2-aminobenzimidazole, 2-hydroxy-3-nitropyridine or 1,2,3,4-tetrahydrocarbazole to generate stable phosphorus ylides. Some ylides exist in solution as a mixture of two geometrical isomers as a result of restricted rotation around the carbon–carbon partical double bond resulting from conjugation of the ylide moiety with the adjacent carbonyl group, whereas others occur as a single isomer only. For this reason, the assignments of more stable Z - or E -isomers as the major or minor forms were investigated using theoretical calculations." @default.
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• W2095437056 date "2010-01-01" @default.
• W2095437056 modified "2023-09-26" @default.
• W2095437056 title "Theoretical study and synthesis of the reaction between triphenylphosphine, dialkyl acetylenedicarboxylates and 2-aminobenzimidazole, 2-hydroxy-3-nitropyridine or 1,2,3,4-tetrahydrocarbazole" @default.
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• W2095437056 doi "https://doi.org/10.1135/cccc2009523" @default.
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