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- W2095448072 abstract "The dinucleating macrocyclic ligands (L2a)2− and (L2b)2− were prepared by [1 : 1] cyclic condensation of N,N′-dipropionitrile-N,N′-ethylene-di(5-methyl-3-formyl-2-hydroxybenzylamine or N,N′-dipropionitrile-N,N′-ethylene-di(5-bromo-3-formyl-2-hydroxybenzylamine with 1,3-diaminopropane. The ligands include dissimilar N(amine)2O2 and N(imine)2O2 coordination sites sharing two phenolic oxygen atoms and containing two propionitrile pendant arms on the amine nitrogen atoms. A series of mono- and dinuclear complexes were synthesized and characterized on the basis of elemental analysis, molar conductance measurement, X-ray crystallography, IR, NMR, and UV-Vis spectroscopies as well as cyclic voltammetric measurements. During the cyclization copper(II) migrates from the N(amine)2O2 to the N(imine)2O2 coordination site and one of the propionitrile pendant arms is removed. The heterodinuclear complexes [ZnL2Cu(OAc)]+ were prepared by a transmetallation reaction. The characterization results showed that the two metal ions are bridged by two phenolic oxygen atoms and an acetate group, providing distorted five-coordinate geometries for both metals." @default.
- W2095448072 created "2016-06-24" @default.
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- W2095448072 date "2012-05-14" @default.
- W2095448072 modified "2023-09-26" @default.
- W2095448072 title "Homo and heterodinuclear complexes derived from unsymmetrical macrocyclic ligands with two coordination sites: removal of a pendant arm and migration of copper ion upon cyclization" @default.
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- W2095448072 doi "https://doi.org/10.1080/00958972.2012.687103" @default.
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