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• W2095461340 startingPage "21735" @default.
• W2095461340 abstract "The phase behaviors of the binary mixture of an anionic surfactant aerosol OT (AOT) and water are investigated on a mesoscopic level using dissipative particle dynamics (DPD) computer simulations. With a simple surfactant model, various aggregation structures of AOT in water including the lamellar, viscous isotropic, and reverse hexagonal phases are obtained, which agree well with the experimental phase diagram. Special attention is given on the unusual lamellar regions. Water diffusivity shows much useful information to understand how the phase behaviors varied with concentration and temperature. It is proposed that the anomalous lamellar phenomena at intermediate AOT concentration (about 40%) are due to the formation of a defective structure, pseudoreversed hexagonal phase, which evidently decreases the water diffusivity. After increasing temperature above 328 K, the pseudoreversed hexagonal structure will be partly transformed to a normal lamellar phase structure and the system lamellar ordering is therefore enhanced." @default.
• W2095461340 created "2016-06-24" @default.
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• W2095461340 date "2006-10-04" @default.
• W2095461340 modified "2023-10-12" @default.
• W2095461340 title "Dissipative Particle Dynamics Simulation of Phase Behavior of Aerosol OT/Water System" @default.
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• W2095461340 doi "https://doi.org/10.1021/jp0623692" @default.
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