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- W2095501725 abstract "Treatment of 2a, b with LiAlH4 gave the [6] and [7]metacyclophanols 4 and 8 in good yields. The reactions of 4 and 8 with MeSO2Cl in the presence of Et3N in CH2Cl2 rapidly proceeded to give the corresponding strained tricyclic ethers 6 and 10, via an intramolecular version of the SN2 reaction. This stereospecific cyclic ether formation in the mesylate molecules 5 and 9 can be rationalized in terms of a short nonbonded length between both reaction centers and a fairly rigid linear relationship between the leaving group and the nucleophilic group." @default.
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- W2095501725 date "1997-05-01" @default.
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- W2095501725 title "Transformation of [6] and [7]metacyclophanols into new strained tricyclic ethers via an intramolecular version of the SN2 reaction" @default.
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- W2095501725 doi "https://doi.org/10.1016/s0040-4039(97)00599-6" @default.
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