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- W2095508085 abstract "Abstract We investigated the hydrogenation properties of layered compound MgB2 mechanically milled under a hydrogen pressure of 1.0 MPa. The total hydrogen concentration after milling for 600 min was approximately 1.0 mass%. No hydrogen insertion into MgB2 interlayer was observed from interlayer distance analysis. On the other hand, mechanical milling generated the nanostructured MgB2 with grain boundary defects in which B–H covalent bond and/or Mg–H bond were assumed to be formed. The nanostructure with grain boundary defects significantly promoted the subsequent high pressure (40.0 MPa) hydrogenation of MgB2 for the synthesis of Mg(BH4)2 comprising [BH4]− anions with B–H covalent bonds." @default.
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- W2095508085 date "2010-09-01" @default.
- W2095508085 modified "2023-10-13" @default.
- W2095508085 title "Nanostructure-induced hydrogenation of layered compound MgB2" @default.
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- W2095508085 doi "https://doi.org/10.1016/j.jallcom.2010.06.101" @default.
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