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- W2095513371 abstract "Samples of bulk amorphous material were prepared in the range from TIS to TIS2.5. Characteristic values of phase transitions (Tg, Tc, Tm) were measured by means of DTA. On this basis the entropies of melting and crystallization were calculated and found to be extremely low in this system (δSm = 1.2 to 1.7 cal/K g-at). A composition- and temperature-dependent solid-to-liquid transition was observed: at room temperature samples with low sulphur content behaved like solids, while samples with high sulphur content behaved more or less like liquids. The TIS2 material which was liquid-like at room temperature was solid at a temperature under 0°C (Tg = 6°C). On the basis of the analysis of radial electron density distribution curves on samples TIS, TIS1.3, TIS2 and TIS2.5 we found, that chains of corner-bound TIS4 tetrahedrons which develop with decreasing sulphur content in a Tl-matrix in which Tl atoms are arranged similarly as in a Tl-layer of the Tl2S structure are responsible for the composition-dependent solidification. The origin of the temperature-dependent liquid-to-solid transformation observed for TIS2 is in the development of TlS bonds of that type which binds a thallium layer to a sulphur one in crystalline Tl2S." @default.
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- W2095513371 date "1978-11-01" @default.
- W2095513371 modified "2023-09-26" @default.
- W2095513371 title "The structure of the amorphous TISx system" @default.
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- W2095513371 doi "https://doi.org/10.1016/0022-3093(78)90066-2" @default.
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