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• W2095536172 abstract "The diastereoselective photodeconjugation of CH2Cl2 solutions of enantiopure ammonium ene-carboxylates was studied and the results compared with those of the enantioselective photodeconjugation of ene-esters in the presence of catalytic amounts of chiral aminoalcohols. We have observed a significant entropic effect and shown that a C-β control of the selectivity is operative in the asymmetric protonation of the photodienolic species." @default.
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• W2095536172 date "2000-05-01" @default.
• W2095536172 modified "2023-10-12" @default.
• W2095536172 title "Asymmetric photodeconjugation of ammonium ene-carboxylates: temperature effects and evidence for the α-carbon of the dienolic species as a latent trigonal centre" @default.
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• W2095536172 doi "https://doi.org/10.1016/s0957-4166(00)00151-8" @default.
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