FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2095536698> ?p ?o ?g. }

• W2095536698 endingPage "6737" @default.
• W2095536698 startingPage "6726" @default.
• W2095536698 abstract "Co(III) corroles were investigated as efficient catalysts for the reduction of dioxygen in the presence of perchloric acid in both heterogeneous and homogeneous systems. The investigated compounds are (5,10,15-tris(pentafluorophenyl)corrole)cobalt (TPFCor)Co, (10-pentafluorophenyl-5,15-dimesitylcorrole)cobalt (F 5PhMes 2Cor)Co, and (5,10,15-trismesitylcorrole)cobalt (Mes 3Cor)Co, all of which contain bulky substituents at the three meso positions of the corrole macrocycle. Cyclic voltammetry and rotating ring-disk electrode voltammetry were used to examine the catalytic activity of the compounds when adsorbed on the surface of a graphite electrode in the presence of 1.0 M perchloric acid, and this data is compared to results for the homogeneous catalytic reduction of O 2 in benzonitrile containing 10 (-2) M HClO 4. The corroles were also investigated as to their redox properties in nonaqueous media. A reversible one-electron oxidation occurs at E 1/2 values between 0.42 and 0.89 V versus SCE depending upon the solvent and number of fluorine substituents on the compounds, and this is followed by a second reversible one-electron abstraction at E 1/2 = 0.86 to 1.18 V in CH 2Cl 2, THF, or PhCN. Two reductions of each corrole are also observed in the three solvents. A linear relationship is observed between E 1/2 for oxidation or reduction and the number of electron-withdrawing fluorine groups on the compounds, and the magnitude of the substituent effect is compared to what is observed in the case of tetraphenylporphyrins containing meso -substituted C 6F 5 substituents. The electrochemically generated forms of the corrole can exist with Co(I), Co(II), or Co(IV) central metal ions, and the site of the electron-transfer in each oxidation or reduction of the initial Co(III) complex was examined by UV-vis spectroelectrochemistry. ESR characterization was also used to characterize singly oxidized (F 5PhMes 2Cor)Co, which is unambiguously assigned as a Co(III) radical cation rather than the expected Co(IV) corrole with an unoxidized macrocyclic ring." @default.
• W2095536698 created "2016-06-24" @default.
• W2095536698 creator A5005466630 @default.
• W2095536698 creator A5008544946 @default.
• W2095536698 creator A5019499764 @default.
• W2095536698 creator A5047789617 @default.
• W2095536698 creator A5049823766 @default.
• W2095536698 creator A5051818947 @default.
• W2095536698 creator A5053954037 @default.
• W2095536698 creator A5066193981 @default.
• W2095536698 creator A5084268749 @default.
• W2095536698 creator A5084664601 @default.
• W2095536698 creator A5091399343 @default.
• W2095536698 date "2008-06-27" @default.
• W2095536698 modified "2023-09-29" @default.
• W2095536698 title "Clarification of the Oxidation State of Cobalt Corroles in Heterogeneous and Homogeneous Catalytic Reduction of Dioxygen" @default.
• W2095536698 cites W1965518970 @default.
• W2095536698 cites W1972642621 @default.
• W2095536698 cites W1974004906 @default.
• W2095536698 cites W1974278281 @default.
• W2095536698 cites W1977457505 @default.
• W2095536698 cites W1980746859 @default.
• W2095536698 cites W1982436014 @default.
• W2095536698 cites W1984362112 @default.
• W2095536698 cites W1990596709 @default.
• W2095536698 cites W1993904532 @default.
• W2095536698 cites W1998147760 @default.
• W2095536698 cites W1999063296 @default.
• W2095536698 cites W1999329526 @default.
• W2095536698 cites W2000067811 @default.
• W2095536698 cites W2001127597 @default.
• W2095536698 cites W2015204681 @default.
• W2095536698 cites W2018193964 @default.
• W2095536698 cites W2023271753 @default.
• W2095536698 cites W2026044872 @default.
• W2095536698 cites W2029974496 @default.
• W2095536698 cites W2031326615 @default.
• W2095536698 cites W2032909203 @default.
• W2095536698 cites W2033507171 @default.
• W2095536698 cites W2037597553 @default.
• W2095536698 cites W2040260467 @default.
• W2095536698 cites W2043461902 @default.
• W2095536698 cites W2044664770 @default.
• W2095536698 cites W2049429496 @default.
• W2095536698 cites W2055267039 @default.
• W2095536698 cites W2057868487 @default.
• W2095536698 cites W2058892496 @default.
• W2095536698 cites W2062982507 @default.
• W2095536698 cites W2066177720 @default.
• W2095536698 cites W2067101667 @default.
• W2095536698 cites W2067445700 @default.
• W2095536698 cites W2068379364 @default.
• W2095536698 cites W2070620969 @default.
• W2095536698 cites W2073685285 @default.
• W2095536698 cites W2076750159 @default.
• W2095536698 cites W2077368656 @default.
• W2095536698 cites W2085778628 @default.
• W2095536698 cites W2092417805 @default.
• W2095536698 cites W2094096354 @default.
• W2095536698 cites W2095048829 @default.
• W2095536698 cites W2103794621 @default.
• W2095536698 cites W2124094579 @default.
• W2095536698 cites W2143981217 @default.
• W2095536698 cites W2147669775 @default.
• W2095536698 cites W2154272673 @default.
• W2095536698 cites W2339332223 @default.
• W2095536698 cites W2951708131 @default.
• W2095536698 cites W3138651176 @default.
• W2095536698 doi "https://doi.org/10.1021/ic800458s" @default.
• W2095536698 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18582035" @default.
• W2095536698 hasPublicationYear "2008" @default.
• W2095536698 type Work @default.
• W2095536698 sameAs 2095536698 @default.
• W2095536698 citedByCount "96" @default.
• W2095536698 countsByYear W20955366982012 @default.
• W2095536698 countsByYear W20955366982013 @default.
• W2095536698 countsByYear W20955366982014 @default.
• W2095536698 countsByYear W20955366982015 @default.
• W2095536698 countsByYear W20955366982016 @default.
• W2095536698 countsByYear W20955366982017 @default.
• W2095536698 countsByYear W20955366982018 @default.
• W2095536698 countsByYear W20955366982019 @default.
• W2095536698 countsByYear W20955366982020 @default.
• W2095536698 countsByYear W20955366982021 @default.
• W2095536698 countsByYear W20955366982022 @default.
• W2095536698 countsByYear W20955366982023 @default.
• W2095536698 crossrefType "journal-article" @default.
• W2095536698 hasAuthorship W2095536698A5005466630 @default.
• W2095536698 hasAuthorship W2095536698A5008544946 @default.
• W2095536698 hasAuthorship W2095536698A5019499764 @default.
• W2095536698 hasAuthorship W2095536698A5047789617 @default.
• W2095536698 hasAuthorship W2095536698A5049823766 @default.
• W2095536698 hasAuthorship W2095536698A5051818947 @default.
• W2095536698 hasAuthorship W2095536698A5053954037 @default.
• W2095536698 hasAuthorship W2095536698A5066193981 @default.
• W2095536698 hasAuthorship W2095536698A5084268749 @default.
• W2095536698 hasAuthorship W2095536698A5084664601 @default.
• W2095536698 hasAuthorship W2095536698A5091399343 @default.

• next