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- W2095563492 abstract "The electrophile-mediated cyclisation of a series of allenic amines (8a-e), carrying a chiral benzylic residue on nitrogen, has been examined using Ag(I) and Pd(II). The cyclised products, (9/10)(using Ag(I)) and (12/13)(using Pd(II), CO, MeOH), are formed diastereoselectively. With Ag(I) up to 81% d.e. has been observed and the stereochemical course of this reaction has been established. The Pd(II)-mediated cyclisation is less selective (up to 43% d.e.) and the factors controlling the selectivities of both of these reactions are discussed." @default.
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- W2095563492 date "1990-01-01" @default.
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- W2095563492 title "Asymmetric synthesis via electrophile-mediated cyclisations" @default.
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- W2095563492 doi "https://doi.org/10.1016/s0040-4020(01)85590-3" @default.
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