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• W2095574719 abstract "9-Diphenylphosphinophenanthrene in solutions at 298 K gives a broad ICT fluorescence spectrum centered at 510 nm in n-hexane. The origin of the ICT fluorescence is discussed on the basis of X-ray structure analysis, solvent effects on fluorescence, and MO calculations by contrast with 9-diphenylaminophenanthrene. The weak interaction between the non-bonding sp3 orbital of the P atom and the π orbital of the phenanthrene moiety in the ground state is considered to promote the intramolecular charge transfer in the excited singlet state, leading to the ICT fluorescence." @default.
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• W2095574719 date "2006-08-01" @default.
• W2095574719 modified "2023-09-24" @default.
• W2095574719 title "Phosphorous atom induced intramolecular charge transfer fluorescence in 9-diphenylphosphinophenanthrene" @default.
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• W2095574719 doi "https://doi.org/10.1016/j.cplett.2006.07.017" @default.
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