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- W2095582021 abstract "pKBH+ Values of a number of 2-aminothiazoles, of their methiodides and of some fixed model imines have been measured in water at 25 °C. In favourable cases this allows the determination of the tautomeric constant KT([amine]/[imine]). Comparison of the results shows that 2-aminothiazoles generally exist in the aminoaromatic form. 2-p-Tosylaminothiazole exists predominantly in the imino-form. 2-Aminothiazoles are generally protonated at the aza-nitrogen while the model imines are protonated at the exocyclic nitrogen. 2-p-Tosyliminothiazoles protonate at the aza-nitrogen as a consequence of the large substituent effect of the tosyl group." @default.
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- W2095582021 date "1982-01-01" @default.
- W2095582021 modified "2023-09-24" @default.
- W2095582021 title "Tautomerism of aminothiazoles. pK BH+ Values of 2-aminothiazoles and of some model imines" @default.
- W2095582021 doi "https://doi.org/10.1039/p29820000535" @default.
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