Matches in SemOpenAlex for { <https://semopenalex.org/work/W2095586170> ?p ?o ?g. }
- W2095586170 endingPage "4128" @default.
- W2095586170 startingPage "4119" @default.
- W2095586170 abstract "The diruthenium μ-allenyl complex [Ru2(CO)(NCMe)(μ-CO){μ-η1:η2-C(H)CC(Me)(Ph)}(Cp)2][BF4], 3b, reacts with halide anions to yield the neutral derivatives [Ru2(CO)2(X){μ-η1:η2-C(H)CC(Me)(Ph)}(Cp)2] [X = Cl, 4b; X = Br, 4c; X = I, 4d]. Complex 4b undergoes isomerization to the unprecedented bridging vinyl-chlorocarbene species [Ru2(CO)(μ-CO){μ-η1:η3- C(Cl)C(H)C(Me)(Ph)}(Cp)2], 10, upon filtration of a CH2Cl2 solution through an alumina column. Complex 3b reacts with an excess of NaBH4 to give five products: the allene complex [Ru2(CO)2{μ-η2:η2- CH2CC(Me)(Ph)}(Cp)2], 5; the hydride species trans-[Ru2(CO)2(μ-H){μ-η1:η2-CHCC(Me)(Ph)}(Cp)2], 6, and cis-[Ru2(CO)2(μ-H){μ-η1:η2-CHCC(Me)(Ph)}(Cp)2], 8; the vinyl-alkylidene [Ru2(CO)(μ-CO){μ-η1:η3- C(H)C(H)C(Me)(Ph)}(Cp)2], 9; and the cluster [Ru3(CO)3(μ-H)3(Cp)3], 7. Studies on the thermal stabilities of 5, 6, 8 and 9 have suggested a plausible mechanism for the formation of these complexes and for the synthesis of 10." @default.
- W2095586170 created "2016-06-24" @default.
- W2095586170 creator A5060566976 @default.
- W2095586170 creator A5062096538 @default.
- W2095586170 date "2007-09-01" @default.
- W2095586170 modified "2023-09-30" @default.
- W2095586170 title "Additions and intramolecular migrations of nucleophiles in cationic diruthenium μ-allenyl complexes" @default.
- W2095586170 cites W1560669034 @default.
- W2095586170 cites W1963596024 @default.
- W2095586170 cites W1967655641 @default.
- W2095586170 cites W1969845049 @default.
- W2095586170 cites W1972319659 @default.
- W2095586170 cites W1982098588 @default.
- W2095586170 cites W1985804147 @default.
- W2095586170 cites W1988631092 @default.
- W2095586170 cites W1988932237 @default.
- W2095586170 cites W1993330524 @default.
- W2095586170 cites W1993858318 @default.
- W2095586170 cites W1994231662 @default.
- W2095586170 cites W1994333835 @default.
- W2095586170 cites W2002585439 @default.
- W2095586170 cites W2006261739 @default.
- W2095586170 cites W2007631082 @default.
- W2095586170 cites W2009801070 @default.
- W2095586170 cites W2010021044 @default.
- W2095586170 cites W2013149717 @default.
- W2095586170 cites W2014041548 @default.
- W2095586170 cites W2018906235 @default.
- W2095586170 cites W2018959865 @default.
- W2095586170 cites W2019060811 @default.
- W2095586170 cites W2020867485 @default.
- W2095586170 cites W2024233826 @default.
- W2095586170 cites W2025063984 @default.
- W2095586170 cites W2026861912 @default.
- W2095586170 cites W2027277996 @default.
- W2095586170 cites W2034028498 @default.
- W2095586170 cites W2038895378 @default.
- W2095586170 cites W2039405137 @default.
- W2095586170 cites W2040282909 @default.
- W2095586170 cites W2047104128 @default.
- W2095586170 cites W2050853819 @default.
- W2095586170 cites W2056255789 @default.
- W2095586170 cites W2058258510 @default.
- W2095586170 cites W2059495561 @default.
- W2095586170 cites W2064192684 @default.
- W2095586170 cites W2067134043 @default.
- W2095586170 cites W2067226639 @default.
- W2095586170 cites W2068278830 @default.
- W2095586170 cites W2072112254 @default.
- W2095586170 cites W2072889478 @default.
- W2095586170 cites W2075236145 @default.
- W2095586170 cites W2077277287 @default.
- W2095586170 cites W2080133072 @default.
- W2095586170 cites W2081791457 @default.
- W2095586170 cites W2084214140 @default.
- W2095586170 cites W2087856162 @default.
- W2095586170 cites W2088829519 @default.
- W2095586170 cites W2092974653 @default.
- W2095586170 cites W2094302071 @default.
- W2095586170 cites W2102410909 @default.
- W2095586170 cites W2120870506 @default.
- W2095586170 cites W2123218232 @default.
- W2095586170 cites W2126435122 @default.
- W2095586170 cites W2128417892 @default.
- W2095586170 cites W2159925451 @default.
- W2095586170 cites W2163526459 @default.
- W2095586170 cites W2275043225 @default.
- W2095586170 cites W2318239768 @default.
- W2095586170 cites W2318511137 @default.
- W2095586170 cites W2324108554 @default.
- W2095586170 cites W2949965259 @default.
- W2095586170 cites W2950001392 @default.
- W2095586170 cites W2950527625 @default.
- W2095586170 cites W4242618042 @default.
- W2095586170 doi "https://doi.org/10.1016/j.jorganchem.2007.06.029" @default.
- W2095586170 hasPublicationYear "2007" @default.
- W2095586170 type Work @default.
- W2095586170 sameAs 2095586170 @default.
- W2095586170 citedByCount "10" @default.
- W2095586170 countsByYear W20955861702013 @default.
- W2095586170 countsByYear W20955861702015 @default.
- W2095586170 countsByYear W20955861702018 @default.
- W2095586170 countsByYear W20955861702022 @default.
- W2095586170 countsByYear W20955861702023 @default.
- W2095586170 crossrefType "journal-article" @default.
- W2095586170 hasAuthorship W2095586170A5060566976 @default.
- W2095586170 hasAuthorship W2095586170A5062096538 @default.
- W2095586170 hasBestOaLocation W20955861702 @default.
- W2095586170 hasConcept C126661725 @default.
- W2095586170 hasConcept C155647269 @default.
- W2095586170 hasConcept C161790260 @default.
- W2095586170 hasConcept C171560689 @default.
- W2095586170 hasConcept C178790620 @default.
- W2095586170 hasConcept C178907741 @default.
- W2095586170 hasConcept C179104552 @default.
- W2095586170 hasConcept C183882617 @default.
- W2095586170 hasConcept C185592680 @default.
- W2095586170 hasConcept C188027245 @default.