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- W2095609667 abstract "AbstractComplexes of Pd(II) and Co(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and Girard T reagent were synthesized, characterized, and their antimicrobial activities were evaluated. The ligand and the complexes were characterized by elemental analysis, IR and NMR spectroscopies, and X-ray crystallography. In both complexes, the deprotonated ligand was coordinated to the metal through the phosphorus, the imine nitrogen, and the carbonyl oxygen atoms. In the octahedral Co(III) complex, two molecules of ligands were coordinated to metal ion, while square-planar environment of Pd(II) complex was constituted of one tridentate ligand and chloride in the fourth coordination place. The ligand and complexes showed moderate antibacterial activity. The molecular structures of the obtained metal complexes and the relative stabilities of two stereoisomers of the ligand were calculated using density functional theory at the S12g/TZ2P level.Keywords: Pd(II) complexCo(III) complexDerivative of 2-(diphenylphosphino)benzaldehydeX-ray structureDFT calculations AcknowledgementExcellent service by the Centre de Serveis Científics i Acadèmics de Catalunya (CESCA) is gratefully acknowledged. Part of this work was supported by COST Action CM1305 “Explicit Control Over Spin-states in Technology and Biochemistry (ECOSTBio).”Additional informationFundingFunding. This work was supported by the Ministry of Education, Science and Technological development of the Republic of Serbia [grant number 172055]. The following organizations are thanked for financial support: the Ministerio de Ciencia e Innovación (MICINN, project number CTQ2011-25086/BQU), and the DIUE of the Generalitat de Catalunya (project number 2014SGR1202 and the XRQTC). Financial support from MICINN (Ministry of Science and Innovation, Spain) and the FEDER fund (European Fund for Regional Development) was provided by grant UNGI08-4E-003." @default.
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- W2095609667 date "2014-10-28" @default.
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- W2095609667 title "Synthesis, characterization, DFT calculations, and antimicrobial activity of Pd(II) and Co(III) complexes with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and Girard’s T reagent" @default.
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- W2095609667 doi "https://doi.org/10.1080/00958972.2014.972389" @default.
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