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- W2095632646 abstract "Evidence based primarily on the technique of collisional activation mass spectrometry is presented which suggests that substituted β-ethyl anions (XCH2CH2–) are at best transient species in the gas phase often rearranging to more stable isomers, e.g., MeCOCH2CH2–→ MeCOCHMe, PhCOCH2CH2–→ PhCOCHMe, HOCOCH2CH2–→ MeCH2CO2– and CH2CHCH2CH2→–CH2–CHCH–Me. The β-methoxycarbonylethyl anion MeOCOCH2CH2– is presumably unstable with respect to its radical since no peak corresponding to either this species or a stable isomer is observed." @default.
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- W2095632646 date "1992-01-01" @default.
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- W2095632646 title "Isomerisation reactions of β-ethyl anions in the gas phase" @default.
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- W2095632646 doi "https://doi.org/10.1039/p29920001815" @default.
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