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• W2095768679 abstract "Asymmetric Pd-catalyzed allylic alkylations of 2-acetoxymalonates with 2-cyclopentenyl chloride are described. With the cymantrene based phosphinooxazoline 2 as chiral ligand enantiomeric excess of > 99% and > 90% yield were obtained. Alkylation products were transformed in three steps to (+)-(3R,3aS,6aS)-3-hydroxy-3,3a,4,6a-tetrahydrocyclopenta[b]furan-2-one (1a) in up to 52 % yield." @default.
• W2095768679 created "2016-06-24" @default.
• W2095768679 creator A5020884635 @default.
• W2095768679 creator A5078827238 @default.
• W2095768679 date "1998-08-01" @default.
• W2095768679 modified "2023-10-17" @default.
• W2095768679 title "First enantioselective synthesis of (+)-(3R,3aS,6aS)-3-hydroxy-3,3a,4,6a-tetrahydrocyclopenta[b]furan-2-one — a versatile chiral heterocyclic building block" @default.
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• W2095768679 doi "https://doi.org/10.1016/s0040-4020(98)00497-9" @default.
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