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- W2095805909 abstract "An efficient selective demethylation and debenzylation method for aryl methyl/benzyl ethers using magnesium iodide under solvent-free conditions has been developed and applied to the synthesis of natural flavone and biphenyl glycosides. A variety of functional groups including glycoside were tolerated under the reaction conditions. Experimental results indicated that the removal of an O-benzyl group was easier than that of an O-methyl group, regardless of wherever they were meta or para to the carbonyl. Thus selective debenzylation can be achieved for substrates bearing both benzyloxy and methoxy groups." @default.
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- W2095805909 date "2009-01-01" @default.
- W2095805909 modified "2023-10-10" @default.
- W2095805909 title "Selective demethylation and debenzylation of aryl ethers by magnesium iodide under solvent-free conditions and its application to the total synthesis of natural products" @default.
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- W2095805909 doi "https://doi.org/10.1039/b916969e" @default.
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