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- W2095852642 abstract "Abstract Interaction of cationic host species, in particular Zn 2+ salts, with polyaza[n]paracyclophanes (i.e. 2,6,9,13-Tetraaza[14]paracyclophane, B323 (1a) ) directs their selective N-functionalization. In this way compounds mono- or difunctionalized with ArCH 2− groups at the benzylic nitrogen atoms can be easily obtained. Direct reaction with the alkylating agent, in the absence of the Zn 2+ species, produces, in general, very complex mixtures of mono- and polyalkylated compounds except when 4-picolyl chloride is used. In this case, mono-, di-, tri- and tetra N-substituted derivatives of D323 can be isolated depending on the amount of the alkylating agent used. In this case, the mono- and dialkylated products obtained differ from the ones prepared using the metal assisted synthesis." @default.
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- W2095852642 date "1997-11-01" @default.
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- W2095852642 title "A remarkable selectivity in the N-functionalization of polyaza[n]paracyclophanes. Synthesis of N-(4-picolyl)-substituted 2,6,9,13-Tetraaza[14]paracyclophanes" @default.
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- W2095852642 doi "https://doi.org/10.1016/s0040-4020(97)10075-8" @default.
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