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- W2095919085 endingPage "872" @default.
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- W2095919085 abstract "The effects of polymerization kinetics and chemical miscibility on the crosslinking structure and mechanical properties of polymers cured by visible‐light initiated free‐radical/cationic ring‐opening hybrid photopolymerization are determined. A three‐component initiator system is used and the monomer system contains methacrylates and epoxides. The photopolymerization kinetics is monitored in situ by Fourier transform infrared‐attenuated total reflectance. The crosslinking structure is studied by modulated differential scanning calorimetry and dynamic mechanical analysis. X‐ray microcomputed tomography is used to evaluate microphase separation. The mechanical properties of polymers formed by hybrid polymerization are comparable to the control formed by free‐radical polymerization. These investigations mark the first time that the benefits of the chain transfer reaction between epoxy and hydroxyl groups of methacrylate, on the crosslinking network and microphase separation during hybrid visible‐light initiated photopolymerization, have been determined. image" @default.
- W2095919085 created "2016-06-24" @default.
- W2095919085 creator A5017997193 @default.
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- W2095919085 creator A5090611064 @default.
- W2095919085 creator A5005817414 @default.
- W2095919085 date "2015-02-11" @default.
- W2095919085 modified "2023-10-12" @default.
- W2095919085 title "Visible-Light Initiated Free-Radical/Cationic Ring-Opening Hybrid Photopolymerization of Methacrylate/Epoxy: Polymerization Kinetics, Crosslinking Structure, and Dynamic Mechanical Properties" @default.
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