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- W2095994472 abstract "The ID coordination polymers, [M I I I (Schiff0base)(dca)] n , dca - = dicyanamide, N(CN) 2 -, M I I I = Mn and Fe, Schiff-base= salen 2 - (N,N'-ethylenebis(salicylaldiminato)) (1) and (2); sal-o-phen 2 - (N,N'-o-phenylenebis (salicylaldiminato)) (3) and (4); (′)-saltch 2 - (N,N'-(′)-trans-cyclohexanebis (salicylaldiminato)) (5) and (6), are reported. The complexes consist of octahedral high-spin M I I I atoms coordinated in the equatorial plane by the tetra-chelating Schiff-base ligand and coordinated in the axial positions by single μ 1 , 5 -dicyanamide bridges, forming infinite linear zigzag chains. The chains of complexes 1 to 6 interdigitate in a parallel fashion with adjacent chains, via weak π-stacking. Variable temperature magnetic susceptibility measurements (2-300 K; H = 1 T) have shown that these compounds display very weak antiferromagnetic coupling, and consequently no long-range magnetic order has been observed under these conditions, as expected for isolated 1D chains." @default.
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- W2095994472 date "2003-09-01" @default.
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- W2095994472 title "ID manganese(III) and iron(III) coordination polymers containing Schiff-base ligands and dicyanamide" @default.
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