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- W2096140522 abstract "Abstract Higher-valent transition metals react with H 2 O 2 to form peroxometallates, thereby activating the coordinated peroxide. Based on the reaction profiles of peroxometal species, environmentally acceptable newer syntheses of tetrabutylammonium tribromide (TBATB), Bu 4 NBr 3 , cetyltrimethylammonium tribromide (CTMATB), cetyl(Me) 3 NBr 3 , and tetraethyl-ammonium tribromide (TEATB), Et 4 NBr 3 , have been developed from the reactions of the corresponding quaternary ammonium bromides with H 2 O 2 and a catalytic amount of vanadium(V) or molybdenum(VI). Other transition metals capable of activating peroxide give similar results. The quaternary ammonium tribromides (QATBs) thus produced, especially TBATB and CTMATB, very efficiently act as clean and selective brominating agents for a variety of organic substrates. Very facile bromination of organic substrates, including aromatics, is also possible by tetrabutylammonium bromide (TBAB) Bu 4 NBr, either promoted by V 2 O 5 H 2 O 2 or catalyzed by MoO 4 2 H 2 O 2 . The scope of the protocols has been underscored, and the relevance to green chemistry has been highlighted." @default.
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- W2096140522 date "2001-01-01" @default.
- W2096140522 modified "2023-10-16" @default.
- W2096140522 title "Peroxometal-mediated environmentally favorable route to brominating agents and protocols for bromination of organics" @default.
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- W2096140522 doi "https://doi.org/10.1351/pac200173010093" @default.
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