Matches in SemOpenAlex for { <https://semopenalex.org/work/W2096153886> ?p ?o ?g. }
- W2096153886 endingPage "384" @default.
- W2096153886 startingPage "373" @default.
- W2096153886 abstract "The interaction of π-electrons in [2,2] phanes was studied both experimentally and theoretically. The fluorescence and phosphorescence spectra were measured at liquid helium temperature; in addition, the zero field splitting parameters D and E were determined by ODMR in zero field and by ordinary ESR at X-band. The results for the phanes with two identical aromatic units can be summarized as follows: The rather small reduction of the D and E values of the order of 10% with respect to the monomers indicates, in agreement with the theoretical treatment given in part II, that the two unpaired electrons of the excited triplet state have a high probability to be at a given time in the same half of the molecule. While the fluorescence spectra show the typical behaviour of emission spectra of dimers or excimers, the phosphorescence spectra exhibit some remaining structure. This behaviour which indicates a somewhat weaker coupling among the triplet orbitals as compared to the singlet orbitals can also be understood on the basis of theoretical considerations. For a phane with two different aromatic units the behaviour is found to be more similar to the corresponding aromatic monomer with the lower excited states with some perturbation by the other part of the phase also in agreement with theoretical expectation." @default.
- W2096153886 created "2016-06-24" @default.
- W2096153886 creator A5004838766 @default.
- W2096153886 creator A5005735752 @default.
- W2096153886 creator A5043022018 @default.
- W2096153886 creator A5071267201 @default.
- W2096153886 creator A5075577778 @default.
- W2096153886 creator A5077971823 @default.
- W2096153886 date "1975-12-01" @default.
- W2096153886 modified "2023-09-26" @default.
- W2096153886 title "Transannular interactions in [2,2] phanes as studied by magnetic resonance and optical spectra" @default.
- W2096153886 cites W1669344267 @default.
- W2096153886 cites W1963677099 @default.
- W2096153886 cites W1967011262 @default.
- W2096153886 cites W1967140358 @default.
- W2096153886 cites W1968935321 @default.
- W2096153886 cites W1969916991 @default.
- W2096153886 cites W1970791594 @default.
- W2096153886 cites W1979860628 @default.
- W2096153886 cites W1982228089 @default.
- W2096153886 cites W1995671317 @default.
- W2096153886 cites W1996200249 @default.
- W2096153886 cites W1999772482 @default.
- W2096153886 cites W2000266972 @default.
- W2096153886 cites W2008717019 @default.
- W2096153886 cites W2017337762 @default.
- W2096153886 cites W2018785797 @default.
- W2096153886 cites W2024406224 @default.
- W2096153886 cites W2032958540 @default.
- W2096153886 cites W2032979334 @default.
- W2096153886 cites W2035804962 @default.
- W2096153886 cites W2036121276 @default.
- W2096153886 cites W2043266242 @default.
- W2096153886 cites W2051306004 @default.
- W2096153886 cites W2055131176 @default.
- W2096153886 cites W2062764352 @default.
- W2096153886 cites W2062808918 @default.
- W2096153886 cites W2062882114 @default.
- W2096153886 cites W2063535117 @default.
- W2096153886 cites W2111550991 @default.
- W2096153886 cites W2114847542 @default.
- W2096153886 cites W2131103614 @default.
- W2096153886 cites W2135228504 @default.
- W2096153886 cites W2148895052 @default.
- W2096153886 cites W2166467201 @default.
- W2096153886 cites W2166574729 @default.
- W2096153886 cites W2321393376 @default.
- W2096153886 cites W2324258662 @default.
- W2096153886 cites W2332394967 @default.
- W2096153886 cites W2332432854 @default.
- W2096153886 doi "https://doi.org/10.1016/0301-0104(75)80056-5" @default.
- W2096153886 hasPublicationYear "1975" @default.
- W2096153886 type Work @default.
- W2096153886 sameAs 2096153886 @default.
- W2096153886 citedByCount "61" @default.
- W2096153886 countsByYear W20961538862014 @default.
- W2096153886 countsByYear W20961538862015 @default.
- W2096153886 countsByYear W20961538862016 @default.
- W2096153886 countsByYear W20961538862019 @default.
- W2096153886 crossrefType "journal-article" @default.
- W2096153886 hasAuthorship W2096153886A5004838766 @default.
- W2096153886 hasAuthorship W2096153886A5005735752 @default.
- W2096153886 hasAuthorship W2096153886A5043022018 @default.
- W2096153886 hasAuthorship W2096153886A5071267201 @default.
- W2096153886 hasAuthorship W2096153886A5075577778 @default.
- W2096153886 hasAuthorship W2096153886A5077971823 @default.
- W2096153886 hasBestOaLocation W20961538862 @default.
- W2096153886 hasConcept C121332964 @default.
- W2096153886 hasConcept C139358910 @default.
- W2096153886 hasConcept C147120987 @default.
- W2096153886 hasConcept C178790620 @default.
- W2096153886 hasConcept C181500209 @default.
- W2096153886 hasConcept C181817918 @default.
- W2096153886 hasConcept C184779094 @default.
- W2096153886 hasConcept C185592680 @default.
- W2096153886 hasConcept C186927785 @default.
- W2096153886 hasConcept C189394030 @default.
- W2096153886 hasConcept C32909587 @default.
- W2096153886 hasConcept C33062035 @default.
- W2096153886 hasConcept C41999313 @default.
- W2096153886 hasConcept C4839761 @default.
- W2096153886 hasConcept C62520636 @default.
- W2096153886 hasConcept C69523127 @default.
- W2096153886 hasConcept C76766466 @default.
- W2096153886 hasConcept C91881484 @default.
- W2096153886 hasConceptScore W2096153886C121332964 @default.
- W2096153886 hasConceptScore W2096153886C139358910 @default.
- W2096153886 hasConceptScore W2096153886C147120987 @default.
- W2096153886 hasConceptScore W2096153886C178790620 @default.
- W2096153886 hasConceptScore W2096153886C181500209 @default.
- W2096153886 hasConceptScore W2096153886C181817918 @default.
- W2096153886 hasConceptScore W2096153886C184779094 @default.
- W2096153886 hasConceptScore W2096153886C185592680 @default.
- W2096153886 hasConceptScore W2096153886C186927785 @default.
- W2096153886 hasConceptScore W2096153886C189394030 @default.
- W2096153886 hasConceptScore W2096153886C32909587 @default.
- W2096153886 hasConceptScore W2096153886C33062035 @default.
- W2096153886 hasConceptScore W2096153886C41999313 @default.