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• W2096156771 abstract "A group of nickel(II) complexes having a square-planar NiS4 co-ordination sphere have been synthesised using the bidentate quinoxaline-2,3-dithiol ligand (H2L1). In dimethylformamide solution the nickel(III)–nickel(II) couple is electrochemically observable for both the thiolate [NiL12]2– and thione [Ni(H2L1)2]2+ complexes with E½ values of +0.12 and +0.32 V respectively vs. saturated calomel electrode. The nickel(III) species can be electrogenerated in solution. Upon freezing (77 K) rhombic EPR spectra (gxx≈ 2.30, gyy≈ 2.05, gzz≈ 2.03) compatible with the uncommon configuration dxy1(g‖ > g⊥) are observed. The fact that the thione (neutral sulfur) complexes are more difficult to oxidise is consistent with the effectiveness of the polarisable sulfur atoms in the thiolate complex, resulting in the stabilisation of NiIII and the observation of relatively low values for the NiII–NiIII potential." @default.
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• W2096156771 date "1993-01-01" @default.
• W2096156771 modified "2023-09-25" @default.
• W2096156771 title "Nickel-(II) and -(III) complexes with NiS4 environments: electron paramagnetic resonance and electrochemical studies" @default.
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• W2096156771 doi "https://doi.org/10.1039/dt9930001159" @default.
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