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• W2096156915 abstract "A new class of π-conjugated polycyclic hydrocarbons that promises interesting electronic properties is presented. The synthesis and extension of the S,N-heteroacene series consisting of only five-membered heterocyclic rings up to a very long, stable, and still soluble decacene SN10 is realized by multiple Pd-catalyzed aminations of halogenated thiophene precursors as key reactions. These novel heteroacenes were characterized by optical spectroscopy and electrochemistry providing interesting structure-property relationships. Nearly complete bond-length equalization in the inner part of the conjugated backbone and an unusual herringbone packing in the solid state underline the structural features of these novel systems." @default.
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• W2096156915 date "2015-07-01" @default.
• W2096156915 modified "2023-10-08" @default.
• W2096156915 title "Fused Thiophene-Pyrrole-Containing Ring Systems up to a Heterodecacene" @default.
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• W2096156915 doi "https://doi.org/10.1002/anie.201502840" @default.
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