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• W2096173804 abstract "The atmospherically highly relevant methylsulfinyl radical (CH3(O)S˙) readily reacts with molecular triplet oxygen in cryogenic argon matrices containing small amounts of (3)O2. Comparison of experimental and computed IR- and UV/Vis spectra, including isotope exchange, show that the initially formed (3)O2 adduct has the structure of a peroxyl radical (CH3(O)SOO˙), which upon irradiation with UV light isomerizes to the methylsulfonoxyl radical (CH3SO3˙). The latter transforms into the methansulfonic acid radical (˙CH2SO3H) by irradiation with visible light. During the matrix photolysis small amounts of SO3 and the methyl radical were detected indicating competitive direct photodissociation." @default.
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• W2096173804 date "2015-01-01" @default.
• W2096173804 modified "2023-10-14" @default.
• W2096173804 title "Reactions of the methylsulfinyl radical [CH₃(O)S˙] with oxygen (³O₂) in solid argon" @default.
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• W2096173804 doi "https://doi.org/10.1039/c5cc02168e" @default.
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