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- W2096180323 abstract "A new form of delafossite-type AgCoO2+δ was prepared using ion exchange from Na0.75CoO2 in molten AgNO3–NH4NO3 at 175 °C. Its structure was determined by the Rietveld refinement from X-ray powder diffraction measurements (XRD) data; it is hexagonal, space group P63/mmc, a=2.871 and c=12.222 Å. Its structure differs from previously reported AgCoO2 (R3¯m, 3R polytype) by the stacking of Co–O layers; in the new phase, the 2H stacking of the precursor Na0.75CoO2 is consistent with a topotactic ion exchange of Na by Ag. The new phase is found to contain a slight oxygen excess (δ=0.06). Magnetic susceptibility measurements show the absence of magnetic transition and a weak Curie term, consistent with the non-magnetic character of Co3+ ions." @default.
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- W2096180323 date "2008-11-01" @default.
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- W2096180323 title "Topotactic synthesis, structure and magnetic properties of a new hexagonal polytype of silver cobaltate(III) AgCoO2+δ" @default.
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- W2096180323 doi "https://doi.org/10.1016/j.jssc.2008.07.031" @default.
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