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• W2096225620 abstract "The metal dusting behaviour of total 11 nickel- and cobalt-base alloys at 680 °C in a gas of 68%CO31%H21%H2O (aC = 19.0, = 5.4 × 10−25 atm) was investigated. All samples were electropolished and reacted in a thermal cycling apparatus. On the basis of their reaction kinetics, these alloys can be classified into three groups: the first, with rapid carbon uptake and significant metal wastage, consists of alloys of relatively high iron content (AC 66, 800H and NS-163); the second, with intermediate rates, consists of some Co-base alloys (HAYNES 188, HAYNES 25 and ULTIMET) and the third, with very low reaction rates, consists of nickel-base alloys with high chromium levels (601, HAYNES HR 160, 230, G-35 and EN 105). An external chromia scale protected group 3 alloys from carburization and dusting. However, this protective scale was damaged and not rehealed for group 1 and group 2 alloys, allowing carbon attack. In all cases, coke deposited on the surface with two typical morphologies: filaments and graphite particle clusters. Subsurface spinel formation in high iron-content alloys led to rapid dusting due to the significant volume expansion. Alloy carbon permeability was calculated from a simple law of mixtures, and shown to correlate reasonably well with initial dusting rate except for one cobalt-base alloy in which iron spinel formation was significant." @default.
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• W2096225620 date "2011-01-12" @default.
• W2096225620 modified "2023-10-17" @default.
• W2096225620 title "Metal dusting behaviour of several nickel- and cobalt-base alloys in COH₂ H₂ O atmosphere" @default.
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• W2096225620 doi "https://doi.org/10.1002/maco.201005863" @default.
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