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- W2096278100 abstract "Abstract Optically active prolinols can be converted into optically active 3‐fluoropiperidines by treatment with DAST. The reaction often produces 2‐fluoromethylpyrrolidines as byproducts. The ring expansion was also applied to 2‐hydroxypiperidines to produce 3‐fluoroazepanes. The rearrangement proceeds via an aziridinium intermediate. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
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- W2096278100 date "2007-08-10" @default.
- W2096278100 modified "2023-10-13" @default.
- W2096278100 title "Ring Expansion Induced by DAST: Synthesis of Substituted 3-Fluoropiperidines from Prolinols and 3-Fluoroazepanes from 2-Hydroxymethylpiperidines" @default.
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- W2096278100 doi "https://doi.org/10.1002/ejoc.200700237" @default.
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