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- W2096366970 abstract "The synthesis of halogenated and arylated 1H-pyridin-2-ones starting from pyridinium N-(pyridin-2-yl)aminides is described. The synthetic pathway involves the reaction of pyridinium N-(5-bromopyridin-2-yl)aminide, N-(3-bromo-5-chloropyridin-2-yl)aminide or N-(3,5-dibromopyridin-2-yl)aminide with different boronic acids to afford monosubstituted and disubstituted aminides in good yields. An additional bromination in the 3-position of N-(5-arylpyridin-2-yl)aminides was performed. Finally, reduction of the N–N bond followed by the reaction of the corresponding 2-aminopyridines with sodium nitrite/sulfuric acid in water yields 3,5-disubstituted 1H-pyridin-2-ones in good yields." @default.
- W2096366970 created "2016-06-24" @default.
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- W2096366970 date "2013-11-08" @default.
- W2096366970 modified "2023-10-18" @default.
- W2096366970 title "ChemInform Abstract: A Facile Synthesis of 3,5-Halo and Aryl 1H-Pyridin-2-ones from Pyridinium N-(Pyridin-2-yl)aminide." @default.
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- W2096366970 doi "https://doi.org/10.1002/chin.201348161" @default.
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