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- W2096477666 abstract "[16656-82-9] C8F12O8Pb (MW 659.13) InChI = 1S/4C2HF3O2.Pb/c4*3-2(4,5)1(6)7;/h4*(H,6,7);/q;;;;+4/p-4 InChIKey = HBKZSKSQIPBOLP-UHFFFAOYSA-J (functionalization of saturated hydrocarbons;2 trifluoroacetoxylation, plumbation, and dimerization of substituted benzene derivatives;3, 4 oxidation of alkenic compounds5) Alternate Name: lead tetrakis(trifluoroacetate); LTTFA. Physical Data: too hygroscopic for mp determination. Solubility: reacts with aliphatic and aromatic hydrocarbons (such as heptane, benzene, toluene, etc.), but is stable and sol in trifluoroacetic acid (TFA), C6F6, CH2Cl2, and MeNO2. Form Supplied in: commercially available in the form of white crystals moistened with TFA. Drying: for some reactions, TFA must be completely removed; this is achieved by drying the reagent in vacuo (over KOH and P2O5) for several days. Analysis of Reagent Purity: the oxidizing capability and purity of the reagent can be determined iodometrically. Preparative Method: can be prepared in situ from Lead(IV) Acetate and Trifluoroacetic Acid. Handling, Storage, and Precautions: the solid reagent is very reactive and hygroscopic, and must be stored in the dark, in the absence of moisture, and below 10 °C." @default.
- W2096477666 created "2016-06-24" @default.
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- W2096477666 date "2001-04-15" @default.
- W2096477666 modified "2023-10-01" @default.
- W2096477666 title "Lead(IV) Trifluoroacetate" @default.
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- W2096477666 doi "https://doi.org/10.1002/047084289x.rl009" @default.
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