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- W2096494203 abstract "Kinetic studies on the reaction between [Fe6S9(SEt)2]4− and PhS− in the presence of [NHEt3]+ to form [Fe6S9(SPh)2]4− are consistent with an acid-catalyzed dissociative mechanism involving rapid protonation of the cluster at both an ethanethiolate and µ n -S, followed by rate-limiting dissociation of the coordinated ethanethiol, and finally rapid attack of PhSH at the vacant site to form the product. Analysis of the kinetic data gives the pK a of [Fe6S9(SEt)2]4− as 17.9, in line with other synthetic Fe–S-based clusters and consistent with protonation of a µ n -S in the cluster core. Further kinetic studies have indicated that Cl−, CN−, ButNC, or imidazole can bind and influence the lability of the cluster." @default.
- W2096494203 created "2016-06-24" @default.
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- W2096494203 date "2010-03-03" @default.
- W2096494203 modified "2023-09-24" @default.
- W2096494203 title "Kinetics and mechanism of the acid-catalyzed substitution reactions of [Fe6S9(SEt)2]4−" @default.
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- W2096494203 doi "https://doi.org/10.1080/00958971003671819" @default.
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