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- W2096543304 abstract "The C3A compacts were hydrated and the reaction was studied by DTA, X-ray diffraction, mercury porosimetry, and volume change analysis. The hexagonal hydroaluminates C2AH8 and C4AH19 formed at 2°, 12°, and 23°C by a direct mechanism between C3A and H2O. The hydration reaction at 52° and 80°C was stopped by formation of C3AH6 around the C3A grains. The rate of conversion of the hexagonal hydrates to cubic C3AH6 increased with temperature. Volume change analysis confirmed that C3AH6 grows epitaxially on the surface of the C3A grain. The reaction at this surface and the passage of water through the layer of hexagonal hydroaluminates control the overall reaction rate. The conversion of the hexagonal hydrates to C3AH6 accelerates the reaction by removing the layer of products from around the C3A grain by a solution mechanism. At 52° and 80°C, C3AH6 may form without the intermediate formation of the hexagonal hydrate." @default.
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- W2096543304 date "1966-05-01" @default.
- W2096543304 modified "2023-09-24" @default.
- W2096543304 title "Character of Hydration of 3CaO.Al2O3" @default.
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- W2096543304 doi "https://doi.org/10.1111/j.1151-2916.1966.tb13255.x" @default.
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