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• W2096571720 abstract "The reactivity of the 2-phosphaethynolate anion (PCO−) towards a cyclic trisilene (cSi3(Tip)4) is reported. The result is the net activation of the PC and SiSi multiple bonds of the precursors affording a heteroatomic bicyclo[1.1.1]pentan-2-one analogue ([P(CO)Si3(Tip)4]−; 1). This reaction can be interpreted as the formal addition of a phosphide and a carbonyl across the SiSi double bond. Photolytic decarbonylation of 1 results in the incorporation of the phosphide vertex into the cyclotrisilene scaffold, yielding a congener of the cyclobutene anion with considerable allylic character." @default.
• W2096571720 created "2016-06-24" @default.
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• W2096571720 date "2014-11-21" @default.
• W2096571720 modified "2023-10-17" @default.
• W2096571720 title "Phosphide Delivery to a Cyclotrisilene" @default.
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• W2096571720 doi "https://doi.org/10.1002/anie.201409908" @default.
• W2096571720 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4506556" @default.
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