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- W2096589870 abstract "Abstract When treated with a reagent prepared from equimolar quantities of methyllithium and copper iodide, 7,21-di-O-TMS bafilomycin A 2 3 undergoes ring expansion to give the 18-membered lactone homolog 5 in nearly quantitative yield. Acid hydrolysis gives iso -bafilomycin A 1 . Ring contraction to the original 16-membered lactone takes place in the presence of fluoride ion. A mechanistic rationale and X-ray crystallographic evidence are presented." @default.
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- W2096589870 title "An unprecedented ring expansion in the Macrolide series - synthesis of iso-bafilomycin A1" @default.
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- W2096589870 doi "https://doi.org/10.1016/s0040-4039(00)73508-8" @default.
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