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- W2096597712 abstract "We consider liquid-vapor systems in finite-volume V⊂d at parameter values corresponding to phase coexistence and study droplet formation due to a fixed excess δN of particles above the ambient gas density. We identify a dimensionless parameter Δ ∼ (δN)(d + 1)/d/V and a universal value Δc = Δc(d), and show that a droplet of the dense phase occurs whenever Δ > Δc, while, for Δ < Δc, the excess is entirely absorbed into the gaseous background. When the droplet first forms, it comprises a non-trivial, universal fraction of excess particles. Similar reasoning applies to generic two-phase systems at phase coexistence including solid/gas—where the droplet is crystalline—and polymorphic systems. A sketch of a rigorous proof for the 2D Ising lattice gas is presented; generalizations are discussed heuristically." @default.
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- W2096597712 date "2002-10-01" @default.
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- W2096597712 title "On the formation/dissolution of equilibrium droplets" @default.
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- W2096597712 doi "https://doi.org/10.1209/epl/i2002-00312-y" @default.
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