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- W2096667414 abstract "The changes in the polymerization rates induced by the elimination or replacement of soluble organometallic co-catalysts have been examined in the course of the polymerization of propene initiated with titanium trichloride and various types of organometallic co-catalysts. The elimination of an organometallic co-catalyst, A, in the liquid phase during the polymerization resulted in a slow deactivation of the catalysts by the attack of a propene monomer. In contrast, the replacement of an initial organometallic co-catalyst, A, by a different co-catalyst, B, during the polymerization caused a rapid change in the polymerization rate from the specific rate with TiCl3 and A to that with TiCl3 and B. These results have been interpreted in terms of the bimetallic mechanism that an organometallic co-catalyst coordinates to a titanium ion, in an exchangeable form with the co-catalysts in the liquid phase, and regulates the catalytic activity." @default.
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- W2096667414 date "1979-09-04" @default.
- W2096667414 modified "2023-09-23" @default.
- W2096667414 doi "https://doi.org/10.1002/macp.1979.021800909" @default.
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