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- W2096738197 abstract "Abstract The Sr 1.32 Mn 0.83 Cu 0.17 O 3 compound has been prepared by solid state reaction in an evacuated sealed silica tube at 1000 °C. The crystal structure of Sr 1.32 Mn 0.83 Cu 0.17 O 3 was studied by means of electron diffraction, high resolution electron microscopy and was refined from X-ray powder diffraction data ( R I =0.042, R P =0.016). The compound belongs to the A 3 m +3 n A′ n B 3 m + n O 9 m +6 n family of hexagonal perovskites. Its incommensurate composite structure ( a =9.5964(1) A, c =2.6001(1) A, q =0.66159(3) c ∗ , superspace group R 3 m(00γ)0s) consists of the modulated [(Mn,Cu)O 3 ] ∞ and [Sr] ∞ subsystems. The repeat period along the [(Mn,Cu)O 3 ] ∞ chains of the BO 6 octahedra and the A′O 6 trigonal prisms is equal to 99 polyhedra and can be represented as a sequence of 1×(3 oct +1 prism ) and 9×(2 oct+1 prism) or 10×(2 oct +1 prism ) . Mn is located at the octahedral sites, whereas the trigonal prismatic sites are randomly occupied by Mn and Cu." @default.
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- W2096738197 date "2003-08-01" @default.
- W2096738197 modified "2023-09-25" @default.
- W2096738197 title "Synthesis and structural investigations on the new Sr1.32Mn0.83Cu0.17O3 compound" @default.
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- W2096738197 doi "https://doi.org/10.1016/s1293-2558(03)00141-9" @default.
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