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- W2096758344 abstract "The voltammetric behaviour of bi- and mono-nuclear complexes formed in solution by Cu(2+) with three polyazacyclophanes containing pyrazole units in aqueous solution is described. Cyclic and square wave voltammetric responses at glassy carbon electrodes indicate that the reduction of copper-macrocycle complexes in solution takes place in two successive one-electron per Cu transfer processes coupled with preorganization and protonation reactions that mimic the behaviour of superoxide dismutase. The electrochemistry of ternary Cu(2+)-receptor-dopamine complexes exhibits significant differences with respect to the protection of the neurotransmitter from post-electron transfer cyclization reactions." @default.
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- W2096758344 date "2006-01-01" @default.
- W2096758344 modified "2023-10-18" @default.
- W2096758344 title "Electrochemistry of copper complexes with macrocyclic polyamines containing pyrazole units" @default.
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- W2096758344 doi "https://doi.org/10.1039/b607296h" @default.
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