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• W2096859957 abstract "Abstract A general methodology for the stereoselective synthesis of 2‐(2‐hydroxyalkyl)piperidine alkaloids by ring‐rearrangement metathesis of nitroso Diels–Alder cycloadducts is reported. The approach is illustrated by the formal synthesis of porantheridine and the total synthesis of andrachcinidine through a diastereodivergent allylation of an N ‐alkoxy bicyclic lactam. The asymmetric synthesis of the latter alkaloid provides new insights into the configurational stability of cycloadducts between chloronitroso reagents and cyclopentadiene." @default.
• W2096859957 created "2016-06-24" @default.
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• W2096859957 date "2013-06-05" @default.
• W2096859957 modified "2023-10-17" @default.
• W2096859957 title "Stereodivergent Synthesis of Piperidine Alkaloids by Ring‐Rearrangement Metathesis/Reductive Lactam Alkylation of Nitroso Diels–Alder Cycloadducts" @default.
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• W2096859957 doi "https://doi.org/10.1002/chem.201300836" @default.
• W2096859957 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23740869" @default.
• W2096859957 hasPublicationYear "2013" @default.
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