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• W2096885367 abstract "Many boronic acids, including 2-heterocyclic, vinyl, and cyclopropyl derivatives, are inherently unstable, which can limit their benchtop storage and/or efficient cross-coupling. We herein report the first general solution to this problem: in situ slow release of unstable boronic acids from the corresponding air-stable MIDA boronates. This remarkably general approach has transformed all three classes of these unstable boronic acids into shelf-stable and highly effective building blocks for cross-coupling with a wide range of aryl and heteroaryl chlorides." @default.
• W2096885367 created "2016-06-24" @default.
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• W2096885367 date "2009-04-30" @default.
• W2096885367 modified "2023-10-09" @default.
• W2096885367 title "A General Solution for Unstable Boronic Acids: Slow-Release Cross-Coupling from Air-Stable MIDA Boronates" @default.
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• W2096885367 doi "https://doi.org/10.1021/ja901416p" @default.
• W2096885367 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7309699" @default.
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