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- W209694078 abstract "A semi-phenomenological model is presented capable to describe with use of the analytical formulae the wideband dielectric and FIR spectra of ordinary and heavy water. In the model two stochastic processes are considered: reorientation of the dipoles in the rectangular potential well and (it is the key line of the work) the linear dielectric response due to a time- varying part of the dipole moment. The last factor arises due to vibration of the H-bonded molecules, which contribute mostly to the translational (near 200 cm) band. Previous linear- response molecular models failed to describe this band in heavy water in terms of the complex dielectric permittivity, as well as the whole spectrum in the frequency range from 0 – 1000 cm band. The spatial and time scales characteristic for water determined by both stochastic processes are estimated." @default.
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- W209694078 date "2001-09-01" @default.
- W209694078 modified "2023-09-26" @default.
- W209694078 title "Simplified Molecular Theory of Dielectric Relaxation Due to Vibrating H-Bonded Molecules. Calculation of Wideband (from 0 to 1000 Cm ) Spectra of Ho and Do Water" @default.
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