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- W2097066152 abstract "Biomimetic aromatic ring cleavage: An iron(II)-2-aminophenolate complex (see picture, right) with a tetradentate ligand reacts with dioxygen to cleave the aromatic CC bond of 2-amino-4-tert-butylphenolate to form 4-tert-butyl-2-picolinate. This complex represents a functional model of 2-aminophenol-1,6-dioxygenase (APD) and 3-hydroxyanthranilate-3,4-dioxygenase (HAD). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
- W2097066152 created "2016-06-24" @default.
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- W2097066152 date "2012-11-29" @default.
- W2097066152 modified "2023-10-18" @default.
- W2097066152 title "Aromatic Ring Cleavage of 2-Amino-4-<i>tert</i>-butylphenol by a Nonheme Iron(II) Complex: Functional Model of 2-Aminophenol Dioxygenases" @default.
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- W2097066152 doi "https://doi.org/10.1002/anie.201206922" @default.
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