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- W2097075672 abstract "Calcium carbonate particles with a unique tablet shape were produced by simply aging the prerefrigerated (at 4°C for 24 h) CaCl 2 –gelatin–urea solutions at 70°C for 24 h in ordinary glass media bottles. Gelatin is known to be the denatured collagen. The thermal decomposition of dissolved urea was exploited to provide the Ca 2+ ion and gelatin‐containing solutions with aqueous carbonate ions. Monodisperse CaCO 3 microtablets formed in solution had a mean particle size of 4±2.5 μm. CaCO 3 microtablets were biphasic in nature and comprised of about 93% vaterite and 7% calcite. Identical solutions used without prerefrigeration yielded only trigonal prismatic calcite crystals upon aging at 70°C for 24 h. Prerefrigeration of CaCl 2 –gelatin–urea solutions was thus shown to have a remarkable effect on the particle morphology. Samples were characterized by scanning electron microscopy, Fourier‐transform infrared spectroscopy, and powder X‐ray diffraction." @default.
- W2097075672 created "2016-06-24" @default.
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- W2097075672 date "2009-01-01" @default.
- W2097075672 modified "2023-10-18" @default.
- W2097075672 title "Monodisperse Calcium Carbonate Microtablets Forming at 70°C in Prerefrigerated CaCl<sub>2</sub>-Gelatin-Urea Solutions" @default.
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- W2097075672 doi "https://doi.org/10.1111/j.1744-7402.2008.02252.x" @default.
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