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• W2097086028 abstract "Mono-Schiff base cobalt(II) and manganese(III) complexes with either benzo-10-aza-crown ether pendants (CoL21, MnL21Cl) or morpholino pendants (CoL22, MnL22Cl) have been employed as models for hydrolase enzymes by studying the kinetics of their hydrolysis reactions with p-nitrophenyl picolinate (PNPP). The kinetic mathematical model of PNPP cleavage catalyzed by these complexes was proposed. The effects of complex structures and reaction temperature on the rate of catalytic PNPP hydrolysis have been also examined. The results showed that the rate increases with pH of the buffer solution and four complexes exhibited high activity in the catalytic PNPP hydrolysis. Compared with the crown-free analogy CoL22 and MnL22Cl, the crowned Schiff base complexes (CoL21, MnL21Cl) exhibit higher catalytic activity. The pseudo-first-order-rate (kobs) for the PNPP hydrolysis catalyzed by the complex MnL21Cl containing benzo-10-aza-crown ether is 923-fold higher than that of spontaneous hydrolysis of PNPP at pH=7.00, 25 °C, [S] =2.0×10−4 mol·dm−3." @default.
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• W2097086028 date "2009-02-01" @default.
• W2097086028 modified "2023-09-24" @default.
• W2097086028 title "Hydrolysis ofp-Nitrophenyl Picolinate Catalyzed by Mono-Schiff Base Complexes with Aza-crown Ether or Morpholino Pendants" @default.
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• W2097086028 doi "https://doi.org/10.1002/cjoc.200990061" @default.
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