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• W2097167131 abstract "Abstract Based on a microscopic approach we demonstrate that the unexpected ferromagnetic properties of BaTiO 3 (BTO) or PTO observed recently at room temperature are due to oxygen vacancies at the surface of the nanocrystalline materials. Such vacancies lead to the appearance of Ti 3+ or Ti 2+ ions with nonzero net spin. The resulting different valence states composed of Ti 3+ or Ti 2+ offer a nonzero magnetization which decreases with increasing particle size. The system shows a multiferroic behavior below a critical size of the nanoparticles and the related polarization tends to a saturation value when the particle size is enhanced. (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)" @default.
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• W2097167131 date "2011-09-27" @default.
• W2097167131 modified "2023-09-27" @default.
• W2097167131 title "Origin of ferromagnetism in BaTiO₃ nanoparticles" @default.
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• W2097167131 doi "https://doi.org/10.1002/pssr.201105419" @default.
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