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- W2097233084 abstract "The radical polymerization of vinyl chloride was investigated at 60°C under high pressure up to 5000 bar in benzaldehyde, benzonitrile, toluene, heptane, cyclohexane, and dioxane as solvent. In benzaldehyde and benzonitrile, the polymerizations were depressed by increased pressure. This unusual behavior was explained by the solvent participation and the effect of pressure on the propagating radicals. The crystallinities of polymer obtained in all solvents decreased with increasing pressure, as judged by the absorbance ratio of the infrared spectra. However the effects of pressure on the absorbance ratio of the polymer obtained in benzaldehyde and benzonitrile were not identical with those in the other solvents. These facts also suggest that both solvents play a special role for the solvent participation in the propagating step." @default.
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- W2097233084 date "1978-06-01" @default.
- W2097233084 modified "2023-10-16" @default.
- W2097233084 title "High-pressure polymerization of vinyl chloride" @default.
- W2097233084 doi "https://doi.org/10.1002/pol.1978.170160621" @default.
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